A RhIII–N-heterocyclic carbene complex from metal–metal singly bonded [RhII −RhII] precursor
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چکیده
منابع مشابه
A RhIII–N-heterocyclic carbene complex from metal–metal singly bonded [RhII−RhII] precursor
Metal–metal singly bonded [Rh2(CO)4(acac)2][OTf]2 (1) has been synthesized and characterized by spectroscopic and analytical techniques. A density functional theory (DFT) optimized structure has been computed for the unbridged centro-symmetric structure. Reaction of 1 with PIN.HBr results in the [Rh(PIN)2(H2O)Br][OTf]2 (2) in high yield. The reaction involves metal-oxidation from RhII to RhIII ...
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ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2011
ISSN: 0974-3626,0973-7103
DOI: 10.1007/s12039-011-0161-9